Home > Press > Liverpool scientists construct molecular `knots'
 |
| The molecular `knots' have dimensions of around two nanometers |
Abstract:
Scientists at the University of Liverpool have constructed molecular 'knots' with dimensions of around two nanometers (2 x 10-9 nm) - around 30,000 times smaller than the diameter of a human hair.
Liverpool scientists construct molecular `knots'
Liverpool, UK | Posted on July 20th, 2010Most molecules are held together by chemical bonds between atoms - ‘nano-knots' are instead mechanically bonded by interpenetrating loops. Liverpool scientists have managed to create nanoscale knots in the laboratory by mixing together two simple starting materials - one a rigid aromatic compound and the other a more flexible amine linker.
This is an unusual example of ‘self-assembly', a process which underpins biology and allows complex structures to assemble from more simple building blocks. Each knot is ‘tied' three times: that is, at least three chemical bonds must be broken to untie the knot. A single knot is a complex assembly of 20 smaller molecules.
Professor Andrew Cooper, Director of the University's Centre for Materials Discovery, said: "I was amazed when we discovered these molecules; we actually set out to make something simpler. A complex structure arises out of quite basic building blocks.
"It is like shaking Scrabble tiles in a bag and pulling out a fully formed sentence. These are the surprises which make scientific research so fascinating."
The experimental work was led by Dr Tom Hasell, a Postdoctoral Researcher, who recognized that the data in an experiment to create organic nanocages was anomalous. In particular, the mass of the molecules was twice as high as expected, a result of the complex mechanical interlocking of two molecular sub-units. The team is now focusing on the practical application of these molecules and similar structures - for example, to build molecular ‘machines' which can trap harmful gases and pollutants such as carbon dioxide.
The research, which was published in the journal Nature Chemistry, forms part of a broader five-year programme focusing on the synthesis of new materials for applications such as energy storage and conversion. The project is funded by the Engineering and Physical Sciences Research Council (EPSRC).
####
For more information, please click here
Contacts:
Kate Spark
Head of Public Relations
Phone: work +44 (0) 151 794 2247
Out of hours (cell+44 (0) 7970 247391)
Samantha Martin
Senior Press Officer
Phone: work +44 (0) 151 794 2248
Out of hours (cell+44 (0) 7973 247836)
Sarah Stamper
Press and Marketing Officer
Phone: work +44 (0) 151 794 3044
Out of hours (cell+44 (0) 7970 247396)
Copyright © University of Liverpool
If you have a comment, please Contact us.Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.
Bookmark:
| Related News Press |
News and information
Electrifying results shed light on graphene foam as a potential material for lab grown cartilage June 6th, 2025
Quantum computers simulate fundamental physics: shedding light on the building blocks of nature June 6th, 2025
A 1960s idea inspires NBI researchers to study hitherto inaccessible quantum states June 6th, 2025
Govt.-Legislation/Regulation/Funding/Policy
Electrifying results shed light on graphene foam as a potential material for lab grown cartilage June 6th, 2025
Institute for Nanoscience hosts annual proposal planning meeting May 16th, 2025
Rice researchers harness gravity to create low-cost device for rapid cell analysis February 28th, 2025
Possible Futures
Ben-Gurion University of the Negev researchers several steps closer to harnessing patient's own T-cells to fight off cancer June 6th, 2025
Researchers unveil a groundbreaking clay-based solution to capture carbon dioxide and combat climate change June 6th, 2025
Cambridge chemists discover simple way to build bigger molecules – one carbon at a time June 6th, 2025
A 1960s idea inspires NBI researchers to study hitherto inaccessible quantum states June 6th, 2025
Academic/Education
Rice University launches Rice Synthetic Biology Institute to improve lives January 12th, 2024
Multi-institution, $4.6 million NSF grant to fund nanotechnology training September 9th, 2022
Molecular Machines
First electric nanomotor made from DNA material: Synthetic rotary motors at the nanoscale perform mechanical work July 22nd, 2022
Nanotech scientists create world's smallest origami bird March 17th, 2021
Giant nanomachine aids the immune system: Theoretical chemistry August 28th, 2020
Self Assembly
Diamond glitter: A play of colors with artificial DNA crystals May 17th, 2024
Liquid crystal templated chiral nanomaterials October 14th, 2022
Nanoclusters self-organize into centimeter-scale hierarchical assemblies April 22nd, 2022
Atom by atom: building precise smaller nanoparticles with templates March 4th, 2022
Announcements
Electrifying results shed light on graphene foam as a potential material for lab grown cartilage June 6th, 2025
Quantum computers simulate fundamental physics: shedding light on the building blocks of nature June 6th, 2025
A 1960s idea inspires NBI researchers to study hitherto inaccessible quantum states June 6th, 2025
Environment
Researchers unveil a groundbreaking clay-based solution to capture carbon dioxide and combat climate change June 6th, 2025
Onion-like nanoparticles found in aircraft exhaust May 14th, 2025
SMART researchers pioneer first-of-its-kind nanosensor for real-time iron detection in plants February 28th, 2025
 |
||
 |
||
| The latest news from around the world, FREE | ||
 |
||
|
|
||
| Premium Products | ||
 |
||
|
Only the news you want to read!
Learn More |
||
 |
||
|
Full-service, expert consulting
Learn More |
||
|
|
||