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Atomic Force Microscopy (AFM) images show pinholes in the spiro-MeOTAD when it is first prepared (top) and after air exposure for 24 hours (bottom). The average diameter of the pinholes is about 135 nanometers, with some as large as two microns.

Abstract:
The most popular next-generation solar cells under development may have a problem - the top layer is full of tiny pinholes, researchers at the Okinawa Institute of Science and Technology Graduate University in Japan have found.

Pinholes are Pitfalls for High Performance Solar Cells

Okinawa, Japan | Posted on February 1st, 2015

The majority of high-performance solar cells under development use a combination of materials including perovskite and spiro-MeOTAD. These cells are far cheaper than traditional silicon-based solar cells, and their efficiency has been increasing significantly in the past few years. But perovskite, which is the layer that converts sunlight to electricity, degrades quickly.

OIST researchers believe they have identified a key culprit for this problem.

Miniscule pinholes in the spiro-MeOTAD layer -- so small they cannot be seen even with a light microscope -- may be creating easy pathways for water and other gas molecules in air to diffuse through the thin film and degrade the perovskite.

"These pinholes may play a major role in the degradation of the lifetime of the solar cells," said Zafer Hawash, a PhD student at OIST who discovered the pinholes. His findings were recently published in the journal Chemistry of Materials.

Hawash noticed the pinholes while analyzing how independent components of air, like water, oxygen and nitrogen, interact with spiro-MeOTAD. At first he didn't think they were important, but when he started looking into it, he found no mention of them in the scientific literature.

"No one has really mentioned this," said Hawash, who works in OIST'sEnergy Materials and Surface Sciences Unit. "I started realizing it was something important to report, to let people know these pinholes exist and that we should get rid of them to get better lifetime."

The pinholes appear to be related to how the spiro-MeOTAD layer is usually made - a solution is spin-coated onto a base layer to create a thin film a fraction of the thickness of a human hair. Another preparation method, vacuum evaporation, does not produce the pinholes, but is less convenient to use, explained Dr. Luis Ono, an Energy Materials and Surface Sciences Unit group leader and paper co-author.

The OIST team is looking into how they can eliminate the pinholes while still keeping the cost low, perhaps by tweaking preparation process or adding other ingredients.

"Currently we are making efforts in finding a way to fix the problem of the pinholes," said Professor Yabing Qi, who heads the Energy Materials and Surface Sciences Unit.

This latest finding builds on the Qi's lab ongoing work to overcome the instabilities in perovskite solar cells and develop low-cost solar power.

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About Okinawa Institute of Science and Technology - OIST
The Okinawa Institute of Science and Technology is an interdisciplinary graduate school offering a 5-year PhD program in Science. Over half of the faculty and students are recruited from outside Japan, and all education and research is conducted entirely in English. OIST researchers are conducting multi-disciplinary research in five major areas: Neuroscience, Molecular Sciences, Environmental and Ecological Sciences, Physical Sciences, and Mathematical Computational Sciences. In the six years leading up to graduate school accreditation, OIST received recognition for doing original research and sponsoring innovative international workshops and courses.

The graduate school accepts 20 students per year, creating a very low student to instructor ratio. Students also receive support for living costs, health care, housing, childcare, and other needs that would otherwise distract them from the science. Balancing lectures and lab work, the doctoral program places students in well-funded labs where they work side-by-side with top researchers on state-of-the-art equipment. Frequent visits from internationally-known scientists further enrich the program and provide opportunities for collaboration and exchange. By the time they graduate, students have accumulated not only abstract knowledge and practical skills but also the kind of professional connections necessary to launch their careers as world-class researchers.

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