Home > Press > Scientists uncover chemical transformations in cobalt nanoparticles
 |
| Provided/Robinson lab The evolution schematics of transition from cobalt to cobalt phosphide nanocrystals. |
Abstract:
Understanding the intricacies of how nanoparticles undergo chemical transformations could lead to better ways to tailor their composition, which can lead to advanced material properties.
Scientists uncover chemical transformations in cobalt nanoparticles
Ithaca, NY | Posted on May 24th, 2011Using the Cornell High Energy Synchrotron Source, scientists led by Richard Robinson, assistant professor of materials science and engineering, uncovered exactly what happens when cobalt nanoparticles transform into two phases of cobalt phosphides.
Their work, published in the Journal of Materials Chemistry, was featured by the journal as a "Hot Article" earlier this month.
The effect Robinson's team observed in the cobalt phosphide transitions was a nanoparticle hollowing due to asymmetric diffusivities of cations and anions. In other words, the cations move out from the core faster than anions can diffuse in, leading to a hollow particle.
Other groups have reported on this "Kirkendall" effect, but the Robinson team was the first to show that this hollowing is more complex than previously thought and can be studied as a two-step process. Their work could be used to control this process and produce complex particles with properties tailored for use in energy applications. Metal phosphides have a wide range of properties -- ferromagnetism, superconductivity, catalytic activity and magnetoresistance among them.
The work was done in collaboration with scientists led by Richard Hennig, assistant professor of materials science and engineering. It was supported by King Abdullah University of Science and Technology, the Cornell Center for Materials Research and the Energy Materials Center at Cornell.
####
For more information, please click here
Contacts:
Media Contact:
Blaine Friedlander
(607) 254-8093
Cornell Chronicle:
Anne Ju
(607) 255-9735
Copyright © Cornell University
If you have a comment, please Contact us.Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.
Bookmark:
| Related News Press |
News and information
Sensors innovations for smart lithium-based batteries: advancements, opportunities, and potential challenges August 8th, 2025
Deciphering local microstrain-induced optimization of asymmetric Fe single atomic sites for efficient oxygen reduction August 8th, 2025
Lab to industry: InSe wafer-scale breakthrough for future electronics August 8th, 2025
Chemistry
Cambridge chemists discover simple way to build bigger molecules – one carbon at a time June 6th, 2025
Single-atom catalysts change spin state when boosted by a magnetic field June 4th, 2025
Quantum interference in molecule-surface collisions February 28th, 2025
Chainmail-like material could be the future of armor: First 2D mechanically interlocked polymer exhibits exceptional flexibility and strength January 17th, 2025
Discoveries
Deciphering local microstrain-induced optimization of asymmetric Fe single atomic sites for efficient oxygen reduction August 8th, 2025
ICFO researchers overcome long-standing bottleneck in single photon detection with twisted 2D materials August 8th, 2025
New molecular technology targets tumors and simultaneously silences two ‘undruggable’ cancer genes August 8th, 2025
Simple algorithm paired with standard imaging tool could predict failure in lithium metal batteries August 8th, 2025
Materials/Metamaterials/Magnetoresistance
First real-time observation of two-dimensional melting process: Researchers at Mainz University unveil new insights into magnetic vortex structures August 8th, 2025
Researchers unveil a groundbreaking clay-based solution to capture carbon dioxide and combat climate change June 6th, 2025
A 1960s idea inspires NBI researchers to study hitherto inaccessible quantum states June 6th, 2025
Institute for Nanoscience hosts annual proposal planning meeting May 16th, 2025
Announcements
Sensors innovations for smart lithium-based batteries: advancements, opportunities, and potential challenges August 8th, 2025
Deciphering local microstrain-induced optimization of asymmetric Fe single atomic sites for efficient oxygen reduction August 8th, 2025
Japan launches fully domestically produced quantum computer: Expo visitors to experience quantum computing firsthand August 8th, 2025
ICFO researchers overcome long-standing bottleneck in single photon detection with twisted 2D materials August 8th, 2025
Research partnerships
Lab to industry: InSe wafer-scale breakthrough for future electronics August 8th, 2025
HKU physicists uncover hidden order in the quantum world through deconfined quantum critical points April 25th, 2025
 |
||
 |
||
| The latest news from around the world, FREE | ||
 |
||
|
|
||
| Premium Products | ||
 |
||
|
Only the news you want to read!
Learn More |
||
 |
||
|
Full-service, expert consulting
Learn More |
||
|
|
||